[Purpose]To research upon the structure and pyrolysis of cotton stalk.[Method] In this paper thermogravimetric analysis is adopted to study pyrolysis characteristics on the longitudinal direction of cotton stalk(the stick and the root)and on the traverse direction(the cuticle,cortex and medulla).[Result] Cotton stalk is a material of uneven and irregular texture,and there are great differences in the structure of all these parts on the longitudinal and traverse directions,especially in the contents of different components in each layer.The reaction in the stick and root becomes violent along with the increase in the rising rate of temperature,and carbon yield rate decreases in turn.Besides with the same rising rate of temperature,carbon yield rate of cotton stick is higher than the one of cotton root.Carbon yield rates of cuticle,cortex and medulla decrease in turn while the violence of the reaction in cuticle is less severe than in cortex and medulla.[Conclusion] It has provided theoretical basis for obtaining activated carbon technology of cotton stick.