The oxidation of 200mg/l reactive red X-3B wastewater was studied by a combination of electrodeless ultraviolet lamp and hydrogen peroxide,hydrogen peroxide alone,microwave alone,electrodeless ultraviolet light(UV)-radiation and microwave irradiation alone,respectively.the results showed that the different oxidation methods were that:MW/UV/H2O2>H2O2 alone>MW/UV>MW alone.when treating time was 60 min,The dye solution was decolored completely,and TOC removal was 52.95%.The mechanism of degradation was explored primarily by GC-MS analysis.