[Objective] This study aimed to investigate the effects of different concen- trations of antimony and modifier calcium magnesium phosphate on photosynthetic characteristics of edible amaranth, flowering Chinese cabbage, spinach and flowering Chinese cabbage. [Method] By outdoor potting simulation experiment, soil matrixes containing 10.00, 20.00, 50.00, 70.00 and 100.00 mg/kg antimony (Sb3+) were pre- pared; soil without antimony was used as control (CK). Each pot was loaded with 0.10 kg/kg vegetable special fertilizer, mixed evenly, and divided into two shares: one share was supplemented with 1.75 g/kg modifier calcium magnesium phosphate and mixed evenly; the other share contained no calcium magnesium phosphate. Af- ter the generation of three true leaves, seedlings with uniform growth were trans- planted into the prepared soil matrixes, eights seedlings per pot. Vegetable seedlings were watered regularly to maintain 70% of field capacity. After 45 d, veg- etable plants were harvested and washed clean with distilled water for measurement of indicators of photosynthetic characteristics. [Result] With the increase of antimony concentration, relative chlorophyll content (SPAD value) and net photosynthetic rate of four vegetable species increased first and then declined, while stomatal conduc- tance of vegetable leaves was linearly reduced. [Conclusion] Appropriately adding modifier calcium magnesium phosphate can effectively improve the photosynthetic characteristics of four vegetable species and reduce the toxic effects of heavy metal antimony on vegetables.