In this work,silver nanoparticles were successfully.The particles were characterized by Transmission electron microscope,UV-visible spectroscopy,particle size analyzer.The results show that particles were about 35nm,and ratio between PVP and AgNO3was the key factors of the synthesis process,which can affect the size and shape of silver nanoparticles.The work implied that the method can also be suitable to fabricate other metal nanostructures.