Selecting six indexs of pH, DO, COD, BOD5, ammonia nitrogen and petroleum hydrocarbons in Haihe River Basin of four seasons in 2012 - 2013 for factor analysis, appling Water Quality Pollution Index (API) to evaluate DO, COD, BOD5 and ammonia nitrogen, aims for systematic evluation to water quality of Haihe River Basin The results showed that two stations of B J1 and HB2 were the 1V type of water, others were the V type; Water Quality Pollution Index (API) was 1.44, which illustrated Haihe River Basin in the state of contamination that the degree of pollution exceeded the standard of functional areas. Factor Analysis explained that between COD, DO and NH3-N were significant difference (P〈0.05); principal component analysis showed that, in addition to pH and BOD5, the other indicators were above 0.70; the contribution rate of COD, DO, NH3-N and TPH were higher, petroleum hydrocarbons was 100%, it can be considered that the waters type of pollution was organic pollution, and petroleum hydrocarbon contamination was more prominent.