In this paper, the synchronization of the fractional-order generalized augmented Lti system is investigated. Based on the predictor--corrector method, we obtain phase portraits, bifurcation diagrams, Lyapunov exponent spectra, and Poincar6 maps of the fractional-order system and find that a four-wing chaotic attractor exists in the system when the system pa- rameters change within certain ranges. Further, by varying the system parameters, rich dynamical behaviors occur in the 2.7-order system. According to the stability theory of a fractional-order linear system, and adopting the linearization by feedback method, we have designed a nonlinear feedback controller in our theoretical analysis to implement the synchro- nization of the drive system with the response system. In addition, the synchronization is also shown by an electronic circuit implementation for the 2.7-order system. The obtained experiment results accord with the theoretical analyses, which further demonstrate the feasibility and effectiveness of the proposed synchronization scheme.