The measurement of emissions from the window material of sapphire was performed through multi-wavelength pyrometer and spontaneous spectroscopic techniques in the pressure range of 40 -120 GPa. The results showed that the spectral distribution with wavelength clearly fit well with the grey-body spectrum. We have analyzed the emissions and discovered they mostly came from the shear banding, which is a typical thermal radiation. The radiance intensity changing linearly with time revealed it was a volume effect. All of the data from pyrometer can be explained by the model of Boslough's study, especially for pres- sures over megabar. The color temperature of shocked sapphire changing with increased stress disagrees with the computed melt curve which is likely explained by the differcnt phase structures of sapphire.
A lack of reliable data treatment method has been for several decades the bottleneck of viscosity measurement by disturbance amplitude damping method of shock waves.In this work the finite difference method is firstly applied to obtain the numerical solutions for disturbance amplitude damping behavior of sinusoidal shock front in inviscid and viscous flow.When water shocked to 15 GPa is taken as an example,the main results are as follows:(1) For inviscid and lower viscous flows the numerical method gives results in good agreement with the analytic solutions under the condition of small disturbance(a0/λ=0.02);(2) For the flow of viscosity beyond 200 Pa s(η=κ) the analytic solution is found to overestimate obviously the effects of viscosity.It is attributed to the unreal pre-conditions of analytic solution by Miller and Ahrens;(3) The present numerical method provides an effective tool with more confidence to overcome the bottleneck of data treatment when the effects of higher viscosity in experiments of Sakharov and flyer impact are expected to be analyzed,because it can in principle simulate the development of shock waves in flows with larger disturbance amplitude,higher viscosity,and complicated initial flow.
MA XiaoJuan1,LIU FuSheng1 & JING FuQian2 1 College of Physical Science and Technology,Southwest Jiaotong University,Chengdu 610031,China
First-principles calculations of structural, electronic, optical, elastic, mechanical properties, and Born effective charges of monoclinic HfO2 are performed with the plane-wave pseudopotential technique based on the density-functional theory. The calculated structural properties are consistent with the previous theoretical and experimental results. The electronic structure reveals that monoclinic HfO2 has an indirect band gap. The analyses of density of states and Mulliken charges show mainly covalent nature in Hf-O bonds. Optical properties, including the dielectric function, refractive index, extinction coefficient, reflectivity, absorption coefficient, loss function, and optical conductivity each as a function of photon energy are calculated and show an optical anisotropy. Moreover, the independent elastic constants, bulk modulus, shear modulus, Young's modulus, Poisson's ratio, compressibility, Lam6 constant, sound velocity, Debye temperature, and Born effective charges of monoclinic HfO2 are obtained, which may help to understand monoclinic HfO2 for future work.
A reliable data treatment method is critical for viscosity measurements using the disturbance amplitude damping method of shock waves. In this paper the finite difference method is used to obtain the numerical solutions for the disturbance amplitude damping behaviour of the sinusoidal shock front in a flyer-impact experiment. The disturbance amplitude damping curves are used to depict the numerical solutions of viscous flow. By fitting the experimental data to the numerical solutions of different viscosities, we find that the effective shear viscosity coefficients of shocked aluminum at pressures of 42, 78 and 101 GPa are (1500±100) Pas, (2800±100) Pa.s and (3500±100) Pa.s respectively. It is clear that the shear viscosity of aluminum increases with an increase in shock pressure, so aluminum does not melt below a shock pressure of 101 GPa. This conclusion is consistent with the sound velocity measurement.