The phosphor Y2SiO5:Ce3+ was prepared by a sol-gel method and the particle growth process was investigated by XRD, SEM and TEM. After heating at 400 °C, the as-dried gel became a powder composed of mixed phases of polycrystalline Y2O3 and amorphous SiO2. With an increase in temperature, the crystallinity of Y2O3 improved. The sample quickly changed to the pure Y2SiO5 phase when it was heated at 1400 °C for 10 min. SEM indicated that the as-dried gel consisted of large porous particles. At an annealing tempe...
This review focused on rare earth upconversion nanophosphors (UCNPs), a particular class of emitters whose photoluminescence mechanism is of fundamental difference from that of conventional dyes and semiconductor quantum dots. We in the first section gave a brief summary on a variety of synthetic methodologies developed during the past decades. Instead of presenting an exhaustive reference list, we selected only a few representative examples, illustrating the merits and limits of each involved synthetic route. Then we surveyed the recent progress in the functionalization techniques for these nanomaterials, depicting the modification in microstructures and improvement in properties with respect to the parent nanoparticles. And finally, we emphasized their application in the research fields of biolabeling and energy transfer, narrating their superior performance benefiting from the unique excitation and emission properties.
