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北京市自然科学基金(2051002)

作品数:4 被引量:23H指数:3
相关作者:吴光夏钟慧杨晔申颖洁吴琳琳更多>>
相关机构:中国科学院生态环境研究中心海勃湾发电厂更多>>
发文基金:北京市自然科学基金北京市科技计划项目国家自然科学基金更多>>
相关领域:化学工程环境科学与工程理学更多>>

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Ultravilolet-radiation-induced graft polymerization of acrylamide onto the melt-blown polypropylene filter element by dynamic method被引量:1
2007年
By dynamic method under UV irradiation, commercial melt-blown polypropylene (PPMB) filter element was modified with acrylamide (AAm) using benzophenone (BP) as initiator. Attenuated total reflection-Fourier transform infrared spectroscopy and scanning electron microscope verified that polyacrylamide chain was grafted on the fiber surface of PPMB filter element. Elemental content analysis with energy dispersive X-ray of fibers revealed that the polymerization content in the inner part of filter element was relatively higher than that in the outer. Degree of grafting changed with initiator concentration, monomer concentration, reaction temperature and reached 2.6% at the reaction condition: CBp=0.06 mol/L, CAAm=2.0 mol/L, irradiation time: 80 min, temperature: 60℃. Relative water flux altered with the hydrophilicity and pore size of filter element. In the antifouling test, the modified filter gave greater flux recovery (approximately 70%) after filtration of the water extract of Liuweidihuang, suggesting that the fouling layer was more easily reversible due to the hydrophilic nature of the modified filter.
WU Lin-linWU Guang-xiaXU Shu-guangZHONG HuiSHEN Ying-jieLIU He-zhiHUANG Zheng-mingYANG Xin-boYUAN Zong-huanTANG Lian-yiLIN Xiang-weiZHANG Shao-laiZHANG Wei-jun
Performances of biological aerated filter employing hollow fiber membrane segments of surface-improved poly(sulfone) as biofilm carriers被引量:10
2007年
Using the surface of poly (sulfone) hollow fiber membrane segments as grafted layer, the hydrophilic acrylamide chain was grafted on by UV-photoinduced grafting polymerization. The gained improvement of surface wettability for the modified membrane was tested by measuring the contact-angle as well as FTIR spectra. Then correlation between the hydrophilic ability of support material and the biofilm adherence ability was demonstrated by comparing the pollutant removal rates from urban wastewater via two identical lab-scale up-flow biological aerated filters, one employed the surface wettability modified poly (sulfone) hollow fiber membrane segment as biofilm carder and the other employed unmodified membrane segment as biofilm carder. The experimental results showed that under the conditions of influent flux 5 L/h, hydraulic retention time 9 h and gas to liquid ratio (G/L) 10: 1, the removal rates of chemical oxygen demand (COD) and ammonium nitrogen (NH4^+-N) for the modified packing filter and the unmodified packing filter was averaged at 83.64% and 96.25%, respectively, with the former filter being 5%-20% more than the latter. The effluent concentration of COD, NH4^+-N and turbidity for the modified packing filter was 25.25 mg/L, 2 mg/L and 8 NTU, respectively. Moreover, the ammonium nitrogen removal performance of the filter packing the modified PSF was compared with the other bioreactor packing of an efficient floating medium. The biomass test indicated that the modified membrane matrixes provided better specific adhesion (3310-5653 mg TSS/L support), which gave a mean of 1000 mg TSS/L more than the unmodified membrane did. In addition, the phenomenon of simultaneous denitrification on the inner surface of the support and nitrification on the outer surface was found in this work.
SHEN Ying-jieWU Guang-xiaFAN Yao-boZHONG HuiWU Lin-linZHANG Shao-laiZHAO Xian-hongZHANG Wei-jun
关键词:NITRIFICATIONDENITRIFICATION
新型填料曝气生物滤池去除氮化合物的效果被引量:8
2009年
采用聚丙烯腈中空纤维膜段作为上流式曝气生物滤池的填料,就系统启动期间生物膜的形成以及对生活污水中氮化合物的去除规律进行了研究,并考察了稳定运行阶段的气水比、水力停留时间等对硝化和反硝化的影响。试验发现:在载体的外表面进行硝化反应的同时,其内部还发生了反硝化反应;中空纤维膜段的形状结构和表面特点使其适宜作为生物膜的载体。
申颖洁吴光夏续曙光钟慧吴琳琳杨晔
关键词:上流式曝气生物滤池中空纤维膜气水比
聚砜与丙烯酸的紫外光辐射接枝共聚及其表征被引量:4
2007年
在均相溶液体系下,运用紫外光辐射引发合成了聚砜与丙烯酸的接枝共聚物。用化学滴定、漫反射傅立叶变换红外光谱和热分析等技术对接枝聚合物进行了表征。结果表明:丙烯酸被接枝在聚砜链上;光照时间、单体浓度和光引发剂浓度对接枝率均有较大影响。膜表面接触角的研究表明,接枝共聚物膜的亲水性比改性前有所提高。
华河林吴光夏钟慧
关键词:聚砜丙烯酸接枝共聚
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