The nanometer CeO2 powder was prepared by the method of microwave-assisted heating hydrolysis,and the nanometer CeO2-supported or ordinary CeO2-supported vanadia catalysts with different vanadium loadings(atomic ratios:100V/Ce=0.1,1,4,10,and 20) were prepared by an incipient-wetness impregnation method.Spectroscopic techniques(XRD,FT-IR,Raman and UV-Vis DRS) were utilized to characterize the structures of VOx/CeO2 catalysts.The results showed that the structures of CeO2-supported vanadium oxide catalysts de...
A novel four-way combining catalysts containing double layers was applied to simultaneously remove four kinds of exhaust pollutants (NOx, CO, HC and PM) emitted from diesel engine. The four-way catalysts were characterized using scanning electron microscope (SEM) and Ultraviolet visible diffuse reflectance spectroscopy (UV-Vis DRS). Their catalytic performances were evaluated by temperature-programmed reaction technology. The double layer catalysts could effectively remove the four main pollutants. The highest catalytic activity was given by the two-layered catalysts of La0.6 K0.4CoO3/Al2O3 and W/HZSM-5. Under the simulated exhaust gases conditions, the peak temperature of the soot combustion was 421℃, the maximal conversion of NO to N2 was 74%, the temperature of the HC total conversion was 357℃, and the maximum conversion ratio of CO was 99%.
Jian Liu,Jie Xu,Zhen Zhao,Aijun Duan,Guiyuan Jiang,Yanni Jing State Key Laboratory of Heavy Oil Processing,China University of Petroleum,Beijing 102249,China.