We investigate Autler-Townes splitting in the photoelectron spectra of K2 molecule driven by pump-probe pulses via employing the time-dependent wave packet approach. It is found that the magnitude of Aulter-Townes splitting varies with the wavelength of the intense laser pulse. In particular, the phenomenon of Aulter-Townes splitting vanishes for the far-off resonance of the pump pulse. Also, the split peaks of Autler Townes in the case of resonant pump pulse give us an approach to directly obtaining the transition dipole moment of a molecule.
We theoretically study the statistics of photon emission of single multi-level quantum system by employing the generating functions approach developed recently. The generalized decay constants are included in single multi-level quantum system with quasi-degenerated levels in this work although they are normally neglected in the absence of (quasi-)degeneracies in multi-level quantum system within the rotating wave approximation. The quantum beats, the line shapes and the Mandel's Q parameters, etc. are studied.