Based on the empirical electron theory of solids and molecules (EET), the statistical values of valence electron structure parameters Sn A and SE A which can characterize the properties of alloy phases are calculated, and influences of alloying elements (e.g., V, Nb, Mo, Hf, Zr, Fe, Mn, Co, Cr, Si, and so on) on the phase transition temperature and eutectoid reaction of titanium alloy are discussed with the statistical values of valence electron structure parameters. The research results agree well with real situations.
Coupled with hot-continuous rolling technology and based on the calculation of the finishing rolling impact work in the non-quenched and tempered Si-Mn steel, the calculations of the finishing rolling impact work in the alloying non-quenched and tempered steel with the elements of Cr, Ni, Mo, W, Cu, V, Nb and Ti are studied with the covalent electron number nA of the strongest bond in alloying phases, the smallest electron density difference ?ρ of phase interfaces, and the number of atom states σ (σ′) which keep the interface electron density continuous. The calculated results show that the finishing rolling impact work of the alloying non-quenched and tempered steel intensely depends on strengthening mechanisms. The solution strengthening, interface strengthening, precipita- tion strengthening of pearlite, and dispersion strengthening will result in the decrease of the finishing rolling impact work; the refinement strengthening, the precipitation strength- ening of V, Nb and Ti in α-Fe-C-V(Nb, Ti), and the residual austenite containing Ni on the boundary of α-Fe-C-Ni will increase the impact work; and the increments or decrements can be calculated with nA, ?ρ, σ (σ′) and weights of alloying elements. The calculation formulas of the finishing rolling impact work in this paper are intergraded with the sug- gested ones of the finishing rolling tensile strength, yield strength, and elongation of the non-quenched and tempered steel. The calculated results agree well with the measured ones.
LIU Zhilin1, LIN Cheng1 & GUO Yanchang2 1. Department of Materials and Chemical Engineering, Liaoning Institute of Technology, Jinzhou 121001, China
Based on the hot-continuous rolling technology, the finishing rolling impact work α k of the non-quenched and tempered Si-Mn steel is theoretically calculated with the covalent electron number nA of the strongest bond in alloying phases, and the smallest interface electron density difference Δρ of alloying phase interface and the number of atom states σ which keep the interface electron density continuous. Calculations show that the solution strengthening, the precipitation strengthening, and the interface strengthening will result in the decrease of the finishing rolling impact work α k, and the effects of the number of atom states σ which keep the interface electron density continuous on the finishing rolling impact work α k are different. Taking the impact work and the number of atom states σ 0 keeping the electron density continuous of the phase interface α-Fe/α-Fe-C between α-Fe and α-Fe-C as reference values, the impact work of the interface will increase when σ of some interface is larger than σ 0; otherwise, the impact will decrease. Therefore, the finishing rolling impact work α k can be calculated with the impact value of the refined α-Fe matrix and the influence amounts caused by the solution strengthening, the precipitation strengthening, the interface strengthening, and the number of atom states σ which keep the interface electron density continuous. The calculated results agree well with the measured ones. In this paper, the effect of S on the impact work is also discussed.
LIU Zhilin1, LIN Cheng1 & WANG Ping2 1. Department of Materials and Chemical Engineering, Liaoning Institute of Technology, Jinzhou 121001, China
