In order to find new structural and biologically active compounds, the constituents from the whole plant of Drymaria diandra B1. (Caryophyllaceae) were investigated and three new flavone glycosides, named drymariatins B (1), C (2), and D (3), were isolated by solvent partition, Si gel, sephadex LH-20, and Rp- 18 column chromatography. Using spectroscopic methods, including two-dimensional nuclear magnetic resonance analysis, the structures of these compounds were elucidated as 6-C-(2-deoxy-β-D-fucopyranosyl)- 5,7,4'-trihydroxyl-flavone, 6-C-(2-deoxy-β-D-fucopyranosyl)-7-O-(β-D-glucopyranosyl)-5,4'-dibydroxyl- flavone, and 6-C-(3-keto-β-digitoxopyranosyl)-7-O-(β-D-glucopyranosyl)-5,4'-dihydroxyl-flavone.
<正>Vanillin (4-hydroxy-3-methoxybenzaldehyde) is the major constituent of vanilla beans and is a principle fla...
WANG, Guo-Song CAO, Qiu-E XIONG,Jie DING, Zhong-Tao (Department of Chemistry, Center for Advanced Studies of Medicinal and Organic Chemistry, Yunnan University, Kunming 650091)