A new ligand,3,6-bis(9-O-quinidine)pyridazine((QD)2PYDZ),was synthesized from quinidine and 3,6-dichloropyridazine under mild condition.It can be purified by recrystallization to give the yield of 73%.The use of(QD)2 PYDZ in asymmetric dihydroxylation(AD)of olelfins provided the corresponding chiral vicinal diols with 88~95%chemical yield and the values of enantiomeric excess(ess)are between 75% and 99%.Meanwhile,chiral β-amino alcohols with excellent eantioselectivity and regioselectivity were also achieved when the asymmetric aminohydroxylation(AA)of olefins were catalyzed by the complex(QD)2PYDZ-Os04.Their chemical yields ranged from 52%to 63%.In addition,during the AD reaction of ethyl trans-cinnamate,(QD)2PYDZ can be recovered and reused for five runs without any signilficant loss in its catalytlc efficiency.