Microstnicture variation of spray-formed Si-30%Al alloy during densification process by hot pressing was studied. The results indicate that the microstnicture of as-deposited preforms is fine and homogenous. The primary silicon phases distributing in aluminium matrix evenly are fine and irregular. Aluminium matrix is divided into two groups: supersaturatedα-Al phase orα-Al phase and Al-Si pseudo-eutectic phase or Al-Si eutectic phase. During hot pressing, the primary silicon and the aluminium matrix realign as follows: the primary silicon fractures at a given compressive stress, the particles congregates in microzone with increasing stress, and the aluminium matrix flows and connects in harness. Al-Si pseudo-eutectic phase turns into Al-Si eutectic phase due to the diffusion of atoms during densification process.
A novel 70Si30Al alloy was prepared by the spray forming process for electronic packaging materials. The effect of the ratio of atomization pressure to metal melt mass flux rate (P/M) on the preforms and microstructures of the spray-deposited 70Si30Al alloy was studied. The results indicate that the PIM value has a considerable influence on the formation of the preforms and the optimal value is in the range of 0.209-0.231 MPa/(kg.min^-1). The microstructure of the spray formed 70Si30AI alloy is fine and homogenous. The primary silicon phases distributing in the aluminum matrix evenly are fine and irregular. The aluminum matrix is divided into two groups: supersaturated α-Al phase or α-Al phase and Al-Si pseudoeutectic phase or Al-Si eutectic phase.
Yanguang Wei Baiqing Xiong Yongan Zhang Hongwei Liu Feng Wang Baohong Zhu
The deformation mechanism of the spray formed 70Si30Al alloy was studied by hot compression on a Gleeble-1500 test machine. It is shown that hot deformation of the spray formed 70Si30Al alloy is achieved by liquid flow due to isostatic pressure and movement of solid particles due to shear force. Deformation condition depends on the nucleation rate and closure rate of the cavities. The flow stress slightly varies when the difference between the nucleation rate and closure rate of the cavities is small; however, it decreases when the nucleation rate of the cavities is greater than the closure rate of the cavities.
WEI Yanguang XIONG Baiqing ZHANG Yong'an LIU Hongwei WANG Feng ZHU Baohong