We have studied the transport property of the composites (La0.83Sr0.17 MnO3)1-x(ITO)x [ITO=(In2O3)0.95 (SNO2)0.05], which were fabricated by mechanically mixing La0.83Sr0.17MnO3 and ITO grains. A giant positive magnetoresistance (PMR) has been observed above the Curie temperature Tc for samples with x around 0.40, in addition to the negative magnetoresistanee related to spin-dependent interracial tunnelling below To. For (La0.83Sr0.17MnO3)0.6(ITO)0.4, the magnetoresistive ratio for the PMR can reach 39.3% under a magnetic field H=2.24×10^5A/m. Theoretical analysis suggests that the magnetic-field-induced broadening of the p-n barrier between both kinds of grains and the density of the p-n heterostructures should be responsible for the PMR behaviour.
A carbon supported Pd(Pd/C) catalyst used as the anodic catalyst in the direct formic acid fuel cells(DFAFC) was prepared via the improved complex reduction method with sodium ethylenediamine tetracetate(EDTA) as stabilizer and complexing agent. This method is very simple. The average size of the Pd particles in the Pd/C catalyst prepared with the improved complex reduction method is as small as about 2.1 nm and the Pd particles in the Pd/C catalyst possess an excellent uniformity. The Pd/C catalyst shows a high electrocatalytic activity and stability for the formic acid oxidation.