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国家重点基础研究发展计划(2007CB936203)

作品数:6 被引量:5H指数:1
相关作者:王恩哥白雪冬刘忠范更多>>
相关机构:中国科学院北京大学更多>>
发文基金:国家重点基础研究发展计划国家自然科学基金国家教育部博士点基金更多>>
相关领域:理学一般工业技术电子电信建筑科学更多>>

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6 条 记 录,以下是 1-6
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硼/氮共掺杂使金属性单壁碳纳米管转变成半导体被引量:1
2009年
本研究小组利用硼和氮共掺杂碳纳米管构筑了大量的场效应晶体管,并对其电学性质进行了统计分析研究。结果表明,通过对单壁碳纳米管进行硼和氮共掺杂,样品中半导体性纳米管的比例由67%提升到高于97%。为了深入理解这一重要实验发现,我们利用第一性原理,计算了掺杂对单壁碳纳米管能带结构的调制作用。结果证明,硼和氮共掺杂可使金属性单壁碳纳米管的能隙被打开,转变为半导体性纳米管,但并不改变半导体性碳纳米管的导电属性,从而在理论上解释了硼和氮共掺杂调节碳纳米管能带结构的物理机制。这项工作为纳米管电子和光电子器件走向实际应用提供了一条新途径。
白雪冬王恩哥
关键词:半导体
Nanobarrier-Terminated Growth of Single-Walled Carbon Nanotubes on Quartz Surfaces被引量:1
2009年
Using carbon nanotubes as nanobarriers,the growth of single-walled carbon nanotubes(SWNTs)on a quartz surface can be terminated.First,carbon nanotube nanobarriers were grown on a quartz surface by the gas ow-directed growth mode.Then,the SWNTs were grown on the quartz surface via the lattice-oriented growth mode,in which growth of SWNTs can be terminated by hitting the nanotube nanobarriers.Moreover,using the carbon nanotube nanobarrier as a marker,the mechanism of the growth of SWNTs on the quartz surface can be studied;a base-growth mechanism is indicated.Based on this termination process and the base-growth mechanism,SWNT arrays with controlled lengths can be grown on a quartz surface by xing the sites of bothcatalysts and nanobarriers.
Chaoqun FengYagang YaoJin ZhangZhongfan Liu
Efficient adsorption of As(V) on poly(acrylo-amidino ethylene amine) nanofiber membranes被引量:1
2013年
Poly(acrylo-amidino ethylene amine) (PAEA) nanofiber membranes have been synthesized by combining the electrospinning technique and subsequent chemical modification. The membranes were used to remove As(V) from aqueous solution. The adsorption kinetics, equilibrium isotherms, and pH effect were investigated in batch experiments. The Langmuir isotherm and pseudo second-order kinetic models agree well with the experimental data. The PAEA nanofibers are effective for As(V) adsorption at pH 3. Experimental results showed that the maximum adsorption capacity of the PAEA nanofibers with As(V) is 76.92 mg g-1 , which is much higher than that of the PAEA microfibers (27.62 mg g-1 ). The adsorption rate of PAEA nanofibers is faster than that of PAEA microfibers due to its higher specific surface area. The PAEA nanofibers can be used as an effective adsorbent for the removal of As(V) in aqueous solution due to high adsorption capacity and short adsorption time to achieve equilibrium.
VU DinhthaoLI XiangWANG Ce
关键词:吸附动力学乙烯胺LANGMUIR
Thermal stability of Mg_2 Si epitaxial film formed on Si(111) substrate by solid phase reaction被引量:2
2009年
A single crystalline Mg2Si film was formed by solid phase reaction (SPR) of a Si(111) substrate with an Mg overlayer capped with an oxide layer(s),which was enhanced by post annealing from room temperature to 100℃ in a molecular beam epitaxy (MBE) system.The thermal stability of the Mg2Si film was then systematically investigated by post annealing in an oxygen-radical ambient at 300℃,450℃ and 650℃,respectively.The Mg2Si film stayed stable until the annealing temperature reached 450℃ then it transformed into amorphous MgOx attributed to the decomposition of Mg2Si and the oxidization of dissociated Mg.
王喜娜王勇邹进张天冲梅增霞郭阳薛其坤杜小龙张晓娜韩晓东张泽
关键词:MG2SI
Sb complexes and Zn interstitials in Sb-implanted ZnO epitaxial films
2011年
In the present work, post-annealing is adopted to investigate the formation and the correlation of Sb complexes and Zn interstitials in Sb-ion implanted ZnO films, by using Raman scattering technique and electrical characterizations. The damage of Zn sublattice, produced by ion bombardment process is discerned from the unrecovered E2 (L) peak in annealed high Sb+ dose implanted samples. It is suggested that the Zn sublattice may be strongly affected by the introduction of Sb dopant because of the formation of Sbzn-2Vz,, complex acceptor. The appearance of a new peak at 510 cm-1 in the annealed high dose Sb+ implanted samples is speculated to result from (Zn interstitials-O interstitials) Zni-Oi complex, which is in a good accordance with the electrical measurement. The p-type ZnO is difficult to obtain from the Sb+ implantation, however, which can be realized by in-situ Sb doping with proper growth conditions instead.
刘尧平英敏菊梅增霞李俊强杜小龙A. Yu. Kuznetsovc
关键词:ZNO
单壁碳纳米管的轴向能带工程
2009年
单壁碳纳米管具有优异的电子学特性,是制备新一代高性能集成电路的重要材料.碳纳米管芯片之路存在诸多挑战,包括直径和手性的控制生长方法、金属性和半导体性单壁碳纳米管的分离方法、器件加工与集成方法等.这些课题从本质上讲大多属于化学问题,因此碳纳米管芯片研究为化学家们提供了新的机遇与挑战.过去10年来,我们围绕单壁碳纳米管的轴向能带工程这一研究思路,开展了一系列碳纳米管芯片的基础探索工作,发展了若干有效的单壁碳纳米管局域能带的调控方法,包括温度阶跃生长法、脉冲供料生长法、基底调控法以及形变调控法等.本文系统地阐述了这些局域能带调控方法,为使读者对该领域的研究进展有一个较为全面的了解,文中对其他课题组开展的代表性工作也给予了综述性介绍.
现晓军刘忠范
关键词:碳纳米管CVDCMOS器件
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