Cobalt porphyrin complexes （TPPConIX） （TPP = 5,10,15,20-tetraphenyl-porphyrin; X = halide） in combination with bis（triphenylphosphine） iminium chloride （PPNC1） were used for the eopolymerization of cyelohexene oxide and CO2. The highest turnover frequency of 67.2 h^-1 was achieved after 13 h at 20℃, and the obtained poly（1,2-cyclohexylene carbonate） （PCHC） showed number average molecular weight （Mn） of 10 × 10^3. Though the obtained PCHC showed atactie structure, the m-centered tetrads content reached 58.1% at CO2 pressure of 1.0 MPa, and decreased to 51.9% at CO2 pressure of 6.0 MPa, indicating that it was inclined to form atactic polymer at high CO2 pressure.
