The spectrum characteristics of geoelectric diurnal variation and geoelectric storm have been identified by maximum entropy method, based on geoelectric data from seven stations in the Chinese mainland, including Jiayuguan, Changli and Chongming. The study shows that, in geoelectric diurnal variation, the amplitude of the 12 h semidiurnal wave is the largest, followed in turn by the 24-25 h diurnal wave and the 8 h periodic wave; Geoelectric storm usually occurs in a large-scale space, whose spectrum values are higher than those of geoelectric diurnal variation by 2-3 orders of magnitude. A preliminary interpretation is presented for the generative mechanism of predominant waves in geoelectric field variation.