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国家自然科学基金(20176043)

作品数:17 被引量:124H指数:7
相关作者:伍沅袁军徐成海肖杨张建伟更多>>
相关机构:武汉工程大学武汉化工学院东北大学更多>>
发文基金:国家自然科学基金湖北省新型反应器与绿色化学工艺重点实验室开放基金更多>>
相关领域:化学工程医药卫生理学更多>>

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17 条 记 录,以下是 1-10
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浸没循环撞击流反应器压力波动信号的小波分析被引量:5
2006年
为了深入了解反应器中压力波动的频率特性及产生原因,基于小波变换方法对浸没撞击流反应器中测得的压力波动信号进行分析·从不同尺度上提取信号并计算波动能量,并对压力波动信号在频域上的分布进行分析·确认波动能量主要集中在1kHz之下的范围内,对能量空间分布的分析证明了波动强烈区域是关于轴及关于撞击面对称的·根据强烈波动空间位置的不同将波动频率划分为三个范围,并分析了各范围波动产生的原因·随螺旋桨转数的增加,各尺度的波动能量总体增强,频率分布有一定的变化·对强度的体积积分结果显示主流体旋涡产生的波动能量占主要部分·
孙怀宇徐成海伍沅
关键词:小波变换撞击流反应器
Pressure Fluctuation in the Submerged Circulative Impinging Stream Reactor被引量:14
2006年
Pressure fluctuation in the submerged circulative impinging stream reactor (SCISR) is studied by measuring the dynamic pressure with micro pressure sensors of high accuracy, with water as the process material. Experimental results show that the maximum amplitude of fluctuation can be up to about 1.6kPa. On the power spectra the fluctuation is relatively concentrated in the range of 〈1000Hz, with some weak peeks in acoustic wave range. The space profile of intensive fluctuation region in the reactor is determined. The region is found to take the form of a couple truncated cones of empty core, with coincided bottoms, and is symmetrical with respect to the impinging plane and approximately symmetrical about the axis, essentially independent of u0. The integral intensity of fluctuation increases as the impinging velocity, Uo increasing.
孙怀宇伍沅徐成海
关键词:REACTOR
Micromixing in the Submerged Circulative Impinging Stream Reactor被引量:21
2003年
Micromixing in the submerged circulative impinging stream reactor (SCISR) developed by the authors is investigated with the Bourne's reaction scheme. The values measured for the impinging velocity, u0, under the conditions of SCISR normal operation, only is of the order of 0.1m·s^-1, are much slower than that inferred,suggesting low power requirement for operation. The values of the characteristic time constant for micromixing,tM, determined in the impinging velocity range of 0.184m·s^-1 < u0 < 0.326m·s^-1 are ranged from 192ms to 87 ms, showing that impinging streams promotes micromixing very efficiently. The data follow approximately the relationship of tM∝ u0^-1.5. A comparative study shows that the micromixing performance of SCISR is much better than that of the traditional stirred tank reactor. The tM values predicted with the existing theoretical model are systematically longer than those measured by about 2--3 times, implying that the regularity of impinging streams promoting micromixing is unclear yet.
伍沅肖杨周玉新
关键词:MICROMIXINGREACTOR
撞击流-沉淀法合成纳米羟基磷灰石被引量:4
2006年
目的运用撞击流沉淀法制备法制备纳米羟基磷灰石(HAP)。方法并用X射线衍射、红外光谱、透射电镜对纳米羟基磷灰石进行了表征和形貌分析。结果采用浸没循环撞击流反应器可得到直径15nm、长度50nm~70nm左右的纳米羟基磷灰石棒状颗粒。结论此方法制备的羟基磷灰石,尺寸分布均匀,是制备HAP的好方法。
袁军伍沅郑启新
关键词:撞击流沉淀法羟基磷灰石
Pressure Fluctuation in the Submerged Circulative Impinging Stream Reactor被引量:2
2006年
Pressure fluctuation in the submerged circulative impinging stream reactor (SCISR) is studied by meas- uring the dynamic pressure with micro pressure sensors of high accuracy, with water as the process material. Ex- perimental results show that the maximum amplitude of fluctuation can be up to about 1.6kPa. On the power spectra the fluctuation is relatively concentrated in the range of <1000Hz, with some weak peeks in acoustic wave range. The space profile of intensive fluctuation region in the reactor is determined. The region is found to take the form of a couple truncated cones of empty core, with coincided bottoms, and is symmetrical with respect to the impinging plane and approximately symmetrical about the axis, essentially independent of u0. The integral intensity of fluctua- tion increases as the impinging velocity, u0 increasing.
孙怀宇伍沅徐成海
关键词:PRESSUREFLUCTUATIONIMPINGINGSTREAMSREACTOR
撞击流反应-沉淀法制取纳米二氧化钛影响因素的实验研究被引量:3
2005年
采用浸没循环撞击流反应器(SCISR),通过四氯化钛快速水解沉淀法制备了纳米二氧化钛,研究了浓度、温度、转速、中和时间、煅烧温度以及煅烧时间等因素对纳米二氧化钛粒径的影响。
吴高安王政
关键词:撞击流纳米二氧化钛影响因素
撞击流-微乳液法纳米羟基磷灰石的制备被引量:4
2007年
在一定pH值条件下,采用水溶液(W)/环己烷(O)/OP-10(S)/正辛醇(A)四元反相微乳液体系并结合撞击流技术制备出粒径为20~50nm的针状纳米羟基磷灰石(HA)晶体。红外光谱(IR)、X射线衍射(XRD)和透射电镜(TEM)对羟基磷灰石颗粒进行表征和分析表明:颗粒分散均匀,成针状,沿c轴方向的微晶尺寸约30nm,沿a轴方向为20nm左右。并主要考察了表面活性剂、杂质、反应和静置时间等对HA的微观形貌的影响。
袁军胡洁罗晓刚
关键词:撞击流微乳液羟基磷灰石
撞击流反应合成纳米二氧化锡被引量:1
2008年
在浸没循环撞击流反应器中,以SnCl4·5H2O和尿素为原料,通过均匀沉淀法制备出金红石结构的纳米SnO2,用XRD和TEM等技术对SnO2粉体进行了表征,探讨了反应温度、原料配比、反应时间、煅烧时间及螺旋桨转速等因素对收率的影响。结果表明,反应时间对收率影响较大,而反应温度和螺旋桨转速对收率的影响较小;在最优工艺条件下制备的SnO2粉体粒径在20nm左右,粒径分布窄,分散性良好。
汪铁林王博周玉新伍沅
关键词:撞击流二氧化锡均匀沉淀法
浸没循环撞击流反应器的流场数值模拟被引量:14
2004年
利用通用有限元分析软件ANSYS中的计算流体动力学模块(FLOTRANCFD),对浸没循环撞击流反应器(简称SCISR)的流场进行了模拟和分析·计算结果表明,SCISR流场中各参数关于撞击面完全对称;导流筒上下两侧及撞击区内仍然有死区存在,可以通过增加雷诺数来减小·在撞击区内速度等值线比较密集,即这个区速度梯度比较大,这对于促进湍动混合非常有利·最后,应用计算机压力采集装置对流场进行了压力测试,并与模拟结果进行了比较·
张建伟徐成海伍沅张和平
关键词:撞击流数值模拟流场
浸没循环撞击流反应器的压力脉动特性被引量:21
2005年
The characteristics of pressure fluctuation in a sub me rged circulative impinging stream reactor (SCISR) were experimentally studied.Th e instantaneous signals of pressure fluctuation resulting from the turbulence in the SCISR were measured by sensors and recorded by a computer.The pressure sign als at some special positions were sampled at different rotary speeds of propell er.After analyzing the signals with the Power Spectrum method,it was found that there was an inherent frequency in the dynamic pressure signals.The inherent fr equencies of the point on the impinging plane were greater than 1000 Hz,so the pressure fluctuation was called high-frequency fluctuation.The fluctuation velo cities with high inherent frequency resulted in a strong shear force field,whic h enabled the fluid to mix quickly on the micro-scale and the agglomerates of s olid particles to disperse effectively.
张建伟伍沅舒安庆徐成海
关键词:压力脉动撞击流反应器
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