To compare the adsorption kinetics of Cu, Zn and Cd introduced into red soils simultaneously and sequentially as well as their distribution coefficients, the ability of red soils to retain heavy metals was evaluated by performing batch experiments. The results indicate that Cu is preferentially adsorbed by red soils no matter in simultaneous or in sequential situation. The adsorption amount of Cd is the minimum in simultaneous competitive adsorption experiment. As heavy metals are added into red soils sequentially, the heavy metal adsorptions are relatively hard to reach equilibrium in 2 h. Red soils retain more Cd than Zn, which is opposite to the result in simultaneous adsorption. The addition sequences of heavy metals affect their adsorbed amounts in red soils to a certain extent. The joint distribution coefficients of metals in simultaneous adsorption are slightly higher than those in sequential adsorption.
Batch and soil column experiments were conducted to evaluate the influence of KH2PO4, （NH4）H2PO4and Ca（H2PO4）2on the adsorption and leaching characteristics of Cu and Zn in red soil. The results show that all the three phosphates can greatly improve the adsorption capacity of red soil for Cu and Zn, and the effect of different phosphates on Cu and Zn adsorption follows the order of Ca（H2PO4）2〉KH2PO4〉（NH4）H2PO4. The addition of phosphate has little effect on the mobility of Cu. Ca（H2PO4）2and （NH4）H2PO4 show a strong ability in immobilizing Zn while the immobilization ability of KH2PO4 is much weaker. All the three phosphates are helpful for modifying the partitioning of Cu and Zn from the non-residual phase to the residual phase; however, they could also enhance the contents of Cu and Zn associated with exchangeable and carbonates fractions.
Labile organic carbon （LOC） and carbon management index （CMI）, which are sensitive factors to the changes of environment, can improve evaluating the effect of land management practices changes on soil quality. The objective of this study was to investigate the effects of land use types and landscape positions on soil quality as a function of L0C and CMI. A field study in a small watershed in the red soil hilly region of southern China was conducted, and soil samples were collected from four typical lands （pine forest （PF） on slope land, barren hill （BH） on slope land, citrus orchard （C0） on terrace land and Cinnarnornum Camphora （CC） on terrace land） at a sampling depth of 20 cm. Soil nutrients, soil organic carbon （SOC）, L0C and CMI were measured. Results showed that the L0C and CMI correlated to not only soil carbon but also soil nutrients, and the values of LOC and CMI in different land use types followed the order CC 〉 PF 〉 CO 〉 BH at the upper- slope, while CO 〉 CC 〉 BH 〉 PF at mid-slope and down-slope. With respect to slope positions, the values of LOC and CMI in all the lands were followed the order： upper-slope 〉 down-slope 〉 mid- slope. As whole, the mean values of LOC and CMI in different lands followed the order CC 〉 CO 〉 PF 〉 BH. High CMI and LOC content were found in the terrace lands with broadleaf vegetations. These results indicated that the terracing and appropriate vegetations can increase the carbon input and lability and decrease soil erosion. However, the carbon pools and CMI in these lands were significantly lower than that in reference site. This suggested that it may require a long time for the soil to return to a high~ quality. Consequently, it is an efficient way to adopt the measures of terracing and appropriate vegetations planting in improving the content of LOC and CMI and controlling water and soil loss in fragile ecosystems.
LI Zhong-wuNIE Xiao-dongCHEN Xiao-linLU Yin-meiJIANG Wei-guoZENG Guang-ming
