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国家自然科学基金(40972131)

作品数:8 被引量:134H指数:7
相关作者:琚宜文侯泉林李小诗谭永杰谭静强更多>>
相关机构:中国科学院安徽省煤田地质局中国地质调查局发展研究中心更多>>
发文基金:国家自然科学基金国家重点基础研究发展计划中国科学院战略性先导科技专项更多>>
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8 条 记 录,以下是 1-10
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高煤级煤岩流变作用的谱学研究被引量:7
2015年
为研究高煤级煤岩在不同流变条件下大分子结构的变化特征,对沁水盆地南部高煤级原生结构煤岩及其变温变压流变实验后的煤岩进行了FTIR和激光拉曼光谱测试和分析。结果表明:不同温压条件形成的不同类型流变煤岩的大分子结构和组成具有明显的差别。煤岩变温变压流变实验(温度300~400℃、围压50~100 MPa、应变小于10%和应变速率10^-4~10-7·s^-1)会使其大分子结构产生改变,并实现化学结构重组:当温度为300或350℃,高煤级煤岩易形成脆性流变或脆韧性流变,机械能转化为热能,一些键能较弱的支链和官能团断裂并且结构脱落,产生裂解小分子,其过程以应力降解作用为主,而芳香结构增多,同时出现应力缩聚;而温度上升至400℃以上,高煤级煤岩即可发生韧性流变,次生缺陷发育,机械能转化为应变能,脱落的小分子优先嵌入或吸附在大分子结构的缺陷或表面,脂肪和芳香结构的变化,其过程既有应力降解作用又有应力缩聚作用,而且以应力缩聚作用为主;围压和样品注水状态对大分子结构影响不明显。
于立业琚宜文李小诗
关键词:大分子结构傅里叶变换红外光谱激光拉曼光谱
煤系泥页岩吸附性能研究及其数值建模
<正>页岩气以吸附、游离和溶解三种状态存在于细粒的泥页岩(层)中,吸附气体的含量占总气体含量的20~85%[1-2],因此甲烷的吸附容量是一个重要的反应页岩气潜力的参数。对于煤系泥页岩,页岩气主要以吸附态为主[3],因而...
卜红玲琚宜文
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Spectra response from macromolecular structure evolution of tectonically deformed coal of different deformation mechanisms被引量:18
2012年
Coals with different deformation mechanisms(brittle deformation,brittle-ductile deformation,and ductile deformation) repre-sent different ways in macromolecular structure evolution based on the metamorphism.The evolution of coal structure could affect the occurrence condition of coalbed methane(CBM) because the nanopore structure affected by macromolecular struc-ture is the most important reservoir for CBM.This paper analyzes the evolutions and mechanisms of structure and functional group of tectonically deformed coals(TDCs) collected from Huainan-Huaibei coalfield using X-ray diffraction(XRD),Raman spectroscopy,and Fourier Transform Infrared(FTIR) spectroscopy methods.The results show that the macromolecular struc-ture evolutions of TDC are different from the primary structure coal as a result of the different metamorphic grade and defor-mation mechanisms.The different deformation mechanisms variously affect the process of functional group and polyconden-sation of macromolecular structure.Furthermore,the tectonic deformation leads to secondary structural defects and reduces the structure stability of TDC.The coupled evolution on stacking and extension caused by the changes of secondary structural de-fects results from different deformation mechanisms.We consider that the changes of chemical structure and secondary struc-tural defects are the primary reasons for the various structure evolutions of TDC compared with primary structure coal.
LI XiaoShiJU YiWenHOU QuanLinLIN Hong
关键词:METAMORPHISM
基于矿物组成与有机质含量的富有机质泥页岩岩相研究及其意义
<正>近两年我国对页岩气的兴趣浓厚,政府放开页岩气市场,先后进行了两次页岩气区块招标,一些缺乏油气勘探开发背景的公司开始从事页岩气研究,涉及的区块遍及大江南北,呈现了一片繁荣景象。然而,目前我国在页岩气勘探开发领域的技术...
王国昌Timothy R.Carr琚宜文
不同变形机制构造煤大分子结构演化的谱学响应被引量:11
2012年
构造变形的机制不同对煤岩结构演化具有重要的控制作用,而结构演化的不同会导致煤层气(瓦斯)赋存状态的变化.本文通过对两淮煤田构造煤样品进行的X射线衍射分析,并结合激光Raman光谱和傅立叶红外光谱的讨论,深入研究了不同变质程度和变形机制构造煤的大分子结构以及官能团的演化响应及其机理.结果表明,由于变质程度和变形机制的不同,构造煤大分子结构参数的演化趋势与原生结构煤参数有着明显的差别;不同变形机制对各类官能团的脱落和大分子结构的缩聚有着不同的影响,构造变形作用可以导致煤岩次生结构缺陷的产生并降低构造煤大分子结构稳定性;由于不同变形机制引起的次生结构缺陷变化不同,导致构造煤的大分子结构单元在堆砌方向和延展方向上出现了耦合互补式的演化过程;由构造变形作用导致的化学结构的变化以及次生结构缺陷的产生是造成构造煤与原生结构煤大分子结构变化不同的主要原因.
李小诗琚宜文侯泉林林红
关键词:构造煤变质作用大分子结构
淮北煤田中南部大地热流及其煤层气资源效应被引量:23
2010年
基于淮北煤田中南部的现今地温场分析和所测定的62块样品的热导率,计算了研究区的大地热流值,并绘制了大地热流分布图.结果表明,淮北煤田中南部平均大地热流值约为60mW/m2,与同处华北板块的其他主要能源盆地相比有所差异,而与研究区所处的区域地质构造及深部地质背景密切相关.大地热流分布总体具有东南、中部、西北相对偏高,而东北、西南相对偏低的特点.通过对研究区二叠系煤系地层埋藏深度和温度计算,绘制了二叠系煤系地层底界面的温度分布图,以此将二叠系煤系地层的温度条件、煤层样品的镜质组反射率、煤变质程度以及研究区构造-埋藏演化史等相结合,从地温场的角度出发探讨了淮北煤田中南部二叠系煤层现今可能所处的生气状态.研究表明,淮北煤田二叠系煤系地层较低的现今地温、较高的镜质组反射率、煤级以中高变质煤为主以及煤系沉积后的构造演化等,都比较适合次生生物成因气的生成,而与热成因气、原生生物成因气的生存条件不吻合.
谭静强琚宜文张文永侯泉林谭永杰
关键词:现今地温场热导率大地热流煤层气淮北煤田
Structure and coalbed methane occurrence in tectonically deformed coals被引量:50
2012年
Research on structure of tectonically deformed coals(TDC) is a key issue in coal and gas outburst prevention and coalbed methane(CBM) exploitation.This paper presents a summary on the research progress in TDC's structural-genetic classification,tectonic strain influence on coal microstructure,coal porosity system,coal chemical structure and constituents,and their relationship with the excess coalbed methane.Previous studies suggested that tectonic deformation had significant influence on coal microstructure,coal super microstructure,and even chemical macromolecular structure.The main mechanisms of coal deformation are the tectonic stress degradation and polycondensation metamorphism(dynamical metamorphism).Besides,under different deformation mechanisms,the ultra-and micro-structure and chemical constituents of TDC presented distinct characteristics.Based on these achievements,we propose one possible evolutionary trend of TDC with different deformation mechanisms,and suggest that the coal and gas outburst in the TDC,especially in the mylonitic coals,may be not only controlled by geological structure,but also influenced by the tectonic stress degradation of ductile deformation.Therefore,further study on TDC should be focused on the controlling mechanism of deformation on structure and composition of coal,generation conditions and occurrence state of excess coalbed methane from deformation mechanism of coal.
HOU QuanLinLI HuiJunFAN JunJiaJU YiWenWANG TianKaiLI XiaoShiWU YuDong
基于矿物组成与有机质含量的富有机质泥页岩岩相研究及其意义
<正>近两年我国对页岩气的兴趣浓厚,政府放开页岩气市场,先后进行了两次页岩气区块招标,一些缺乏油气勘探开发背景的公司开始从事页岩气研究,涉及的区块遍及大江南北,呈现了一片繁荣景象。然而,目前我国在页岩气勘探开发领域的技术...
王国昌Timothy R.Carr琚宜文
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盆地滑脱构造及其页岩气赋存研究进展
<正>在中国大陆沉积盖层地层序列中,能干性地层(如灰岩、砂岩等)强度较大,往往构成推覆体或滑覆体的主体;而非能干层(如煤层、页岩层或膏盐层等)则具有更明显的塑性性质,成为滑脱系统中的滑脱层位[1-9]。]沉积岩序列具有多...
琚宜文谭锋奇孙盈吴建光王国昌李小诗鲍园颜志丰于立业卫明明李清光Neupane Bhupati
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Response of Macromolecular Structure to Deformation in Tectonically Deformed Coal被引量:8
2013年
The structural evolution of tectonically deformed coals (TDC) with different deformational mechanisms and different deformational intensities are investigated in depth through X-ray diffraction (XRD) analysis on 31 samples of different metamorphic grades (R : 0.7%-3.1%) collected from the Huaibei coalfield. The results indicated that there are different evolution characteristics between the ductile and brittle deformational coals with increasing of metamorphism and deformation. On the one hand, with the increase of metamorphism, the atomic plane spacing (d002) is decreasing at step velocity, the stacking of the BSU layer (Lc) is increasing at first and then decreasing, but the extension of the BSU layer (La) and the ratio of La/Lc are decreasing initially and then increasing. On the other hand, for the brittle deformational coal, d002 is increasing initially and then decreasing, which causes an inversion of the variation of Lc and La under the lower-middle or higher-middle metamorphism grade when the deformational intensity was increasing. In contrast, in the ductile deformational coals, d002 decreased initially and then increased, and the value of L~ decreased with the increase of deformational intensity. But the value of La increased under the lower-middle metamorphism grade and increased at first and then decreased under the higher-middle metamorphism grade. We conclude that the degradation and polycondensation of TDC macromolecular structure can be obviously impacted during the ductile deformational process, because the increase and accumulation of unit dislocation perhaps transforms the stress into strain energy. Meanwhile, the brittle deformation can transform the stress into frictional heat energy, and promote the metamorphism and degradation as well. It can be concluded that deformation is more important than metamorphism to the differential evolution of the ductile and brittle deformational coals.
LI XiaoshiJU YiwenHOU QuanlinFAN Junjia
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